Hello Ron,
Did you also ask this in a recent GATC case? Someone named "Ronny" with a 7100 switch in routing mode had the same exact question and he was able to get this to work with IP Tables on the NAC, albeit this is not officially supported. Other than the IP Tables, these questions: "It seems like that a proxy redirection with PBR is not possible?" and "Has anyone done a DNS-Redirection with PBR?" should probably got to the switching/routing group.
Regards,
Scott Keene