On your 802.1x Privacy settings tab under WLAN Services, what Key Management Options do you have it set at. Just so you know, and I don't know why, but the Apple Macbook computers do not support Opportunistic Key Caching (OKC), but their iPads/iPhones do. Our Key Mangement Options are set to "Pre-Authentication"
As mentioned before you will need to measure the signal from where this Mac is and look to see what the neighboring AP signal level is at. Because you have it set your radio levels to maximum power, you could be seeing interference from nearby APs. How far off is the next AP where this iMac sits?