You can enter the name server addresses either in the controller profile itself or as a controller override. In either case though, the actual CLI syntax you would use is: ip name-server X.X.X.X
Example, to enter an address as an override:
1) Login
2) enable
3) self
4) ip name-server 8.8.8.8
5) commit write
You can enter multiple DNS entries this way.
From the UI:
1) Configuration Tab
2) Devices
3) Select the RFS6000
4) In center column, expand "Profile Overrides"
5) Expand "Network"
6) Select DNS
7) Over to the right, you should see where you can enter DNS server entries
Remember to "Commit and Save" in the top right corner when done